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Polyferric Sulfate

Chemical Safety Specification

Part One:Chemical Item Name

Chemical item name:Polymeric ferric sulfate

molecular formula: [Fe2(OH)n(SO4)3-n/2]m(n<2, m=f(n))

Technique instruction book code: 1327-41-9

Part Two:Component Information

Injurant: ferric sulfate

Percentage of ferric sulfate: 20—21%

CAS No. ： 1327-41-9

Part Three:Hazard Identification

Health Hazard:irritation to skin and mucosa. High density will cause bronchitis, even bronchial asthma sometimes.Too much absorption will cause mouth cavity, gastritis, gastrorrhagia and  mucosa necrosis.

chronic effect: long-term exposure will cause headache,dizziness, anorexian,cough, rhinobyon and  chest pain.

explosion hazard: non-combustible

Part Four:Emergency Treatment

Skin exposure:take off pollutional clothes at once,wash in flowing water for 15 minutes at least and go to hospital.

Eye exposure:open eyelid and wash in flowing water or normal saline for 15 minutes at least,and go to hospital.

Inhalation:go to breath fresh air and keep the respiratory tract clear.If beath hard, oxygen therapy is needed.if breath stopped,artificial breath must be done at once and go to hopital.

Ingestion:wash mouth and drink some milk or albumen,and go to hospital.

Part Five:Fire protection

Extinguishing method:Firemen must wear full-body anti-acid bases clothes.

Extinguishant:day sandy soil.

Part Six:Leakage Emergency Treatment

First aid treatment:separate the leaking polluted area,control come-in and go-out.Emengency men should wear anti-dust mask,and wear anti-acid bases uniform.Don’t touch the leakage directly.If leakage is small,avoid cause dust,and use clean shovel to gather the leakage in closed container.If the leakage is much:use plastic cloth or canvas to cover it.And clear it away with professional guidance.

Part Seven:Operating and Storing

Operating attention:Operate in airtight condition,and local exhaust.Operation staff must be trained strictly and professionally,and they should obey operation regulations and rules.And operation staff should wear self-absorped,filtered and anti-dust mask,wearing chemical protected glasses,anti-acid bases uniforms and gloves are required.Keep away from the conbustibles and dust.Avoid to expose to soda and alcohol.Especially avoid to be exposed to water.Be careful when being loaded or uploaded,Protect its package and container from being damaged.Equip with leakage handling facilities.And the empty containers are possible to have injurant.

Storing attention:store the chemicals in cool,dry and breeziest warehouse.keep them away from inflammables and heat sources.The humidity should be keeped under 75%.Package must be sealed and dry.They should be stored separately from the combustibles,soda,and alcohol,they mustn’t be mixstored.Avoid storing for a long time,or it will go bad.Warehouse should have some suitable containers to gather the leakage.

Part Eight:Exposure Control and Individual Protection

Occupation Expoure limitation

China MAC(mg/m3):No standard at present

TLVTN：ACGIH 2mg/m3

TLVWN：No regulated standard yet

Project control:operation in airtight condition,local exhaust.Supply safe shower facilities and eye-washing facilities.

Breathing System Protection:When expose to the chemical dust,we should wear self-absorped, filtered,and anti-dust mask,when handling emergency,we suggest air respiratorresuscitator.

Eye protection:Wear chemical-safe protection glasses.

Body protection:Wear rubber anti-acid bases uniform.

Hand protection:Wear rubber anti-acid bases gloves.

Other protection:Forbid smoking,eat and drinking in working area.After work,take shower at once and change clean clothes.Put the hazard polluted clothes seperately and keep good sanitary habit.

Part Nine: Physiochemical Features

Main componet:Pure chemicals

Shape and Properties:Yellow schistose,granularity or solidity.

PH:3.5-5

Melting Point: (℃)：190(253kPa)

Boiling Point:No standard information

Relative Density(water=1):2.44

Relative Steam Density(air=1):No stardard informaiton

Saturation Steam Pressure(kPa)：0.13(100℃)

Heat of Conbustion:No information

Critical Temperature(℃):No information

Critical Pressure(MPa):No information

Octanol/water ratio:No information

Flashing Point(℃):No sense

Combustible Degree(℃):No sense

Explosure Upper Limit%(V/V)：No sense

Explosure Lower Limit%(V/V)：No sense

dissolubility:Soluble with water,alcohol,chloroform,and tetrachloride.

Main usage:innovative, superior and efficient ferric salt inorganic high polymer wadding,mainly used in purifying water,filter aluminim,chlorine and other heavy metal ion hazard.And no iron ion transfering,non toxic and hazard,its safe and reliable. It’s turbidity removal,decoloration,deoiling,dewatering,degerming,deodorization, turbidity removal,and remove COD,BOD,and heavy metal ion.It is also widely used in industrial waste water purifying,such as printing dyeing waste water handling,and also be used in casting,paper making,healing drugs,processing hides,ect.

Part Ten:Stability and Reactivity

Prohibition:Combustibles,soda,water,and alcohol.materials.

Unexposure Condition:Damp air

Polymerization Hazard:No dangerous material

Part Eleven:Toxicology Information

Acute Toxic: LD50：3730 mg/kg

LC50:No information

Part Twelve:Disposal considerations

Disposal Processing Method:Handling according to the state of local laws and regulations.Or according to manufacturer’s advice.

Part Thirteen:Transportation Information

Dangerous Article Code:81045

UN Code:1726

Packing Mark:Rain-proof and damp-proof

Packing Standard:25kg or 50kg/box with plastic polythene bag for inner packing

Transportation Attention:

Should be transported according to 《dangerous articles transportation》regulations edited by Ministry of Railways.Package should be complete to ensure the loading.Make sure the containers have no leakage,no collapse,no breaking and no damage,Mixloading with combustibles,soda,alcoholand food chemicals is forbidden.Transport vehicle should be equiped with emergency handling facilities during transportation.Solorization,rain,high temperature is also should be avoided during transportation.

Part Fourteen:Laws and Regulations Information

Dangerous chemical articles safe control regulations(Issued on Feb 17^th,1987 by State Council),Dangerous chemicals safe control regulation provision([1992]NO.677),Working area safe using chemical regulation ([1996]NO.423),Aimed to safety of using,producing,storing,transportation,loading  dangerous artricles,Many regulations were made to control.